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Auteur J. S. Rowlinson
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Faire une suggestion Affiner la rechercheCohesion : a scientific history of intermolecular forces / J. S. Rowlinson
Titre : Cohesion : a scientific history of intermolecular forces Type de document : document imprimé Auteurs : J. S. Rowlinson, Auteur Editeur : Cambridge, GB : Cambridge University Press Année de publication : 2002 Importance : VIII-333 p. : ill. ; 26 cm ISBN/ISSN/EAN : 0-521-81008-6 Note générale : Hardback
Langues : Français (fre) Cohesion : a scientific history of intermolecular forces [document imprimé] / J. S. Rowlinson, Auteur . - Cambridge, GB : Cambridge University Press, 2002 . - VIII-333 p. : ill. ; 26 cm.
ISBN : 0-521-81008-6
Hardback
Langues : Français (fre)Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Molecular theory of capillarity / J. S. Rowlinson
Titre : Molecular theory of capillarity Type de document : document imprimé Auteurs : J. S. Rowlinson, Auteur ; B. Widom, Auteur Editeur : Mineola, NY : Dover Publications Année de publication : 1989 Importance : XI-327 p. ISBN/ISSN/EAN : 0-486-42544-4 Note générale : Hardback
Langues : Français (fre) Index. décimale : 68 Surfaces and interfaces Résumé : Tracing the history of thought on the molecular origins of surface pheomena, this volume offers a critical and detailed examination and assessment of modern theories. The opening chapters survey the earliest efforts to recapture these phenomena by using crude mechanical models of liquids as well as subsequent quasi-thermodynamic methods. A discussion of statistical mechanics leads to the application of results in mean-field approximation to some tractable but artificial model systems. More realistic models are portrayed both by computer simulation and by approximations of the precise statistical equations. Emphasis throughout the text is consistently placed on the liquid-gas surface, with a focus on liquid-liquid surfaces in the final two chapters. Unabridged republication of the edition published by Oxford University Press, Oxford, 1989. Preface. Principal symbols. Appendixes. Name Index. Subject Index. Table of Contents for Molecular Theory of Capillarity Principal symbols 1 MECHANICAL MOLECULAR MODELS 1.1 Introduction 1.2 Molecular mechanics 1.3 Capillary phenomena 1.4 The internal energy of a liquid 1.5 The continuous surface profile 1.6 The mean molecular field 2 THERMODYNAMCIS 2.1 Thermodynamics and kinetic theory 2.2 The thermodynamics of the surface 2.3 Surface functions 2.4 The spherical surface 2.5 Quasi-thermodynamics-a first look 3 THE THEORY OF VAN DER WAALS 3.1 Introduction 3.2 The surface tension 3.3 Independently variable densities 3.4 Gibbs adsorption equation in the van der Waals theory 3.5 Constraints on the range of fluctuations 4 STATISTICAL MECHANICS OF THE LIQUID-GAS SURFACE 4.1 Introduction 4.2 Distribution and correlation functions 4.3 The pressure tensor 4.4 The virial route to the surface tension 4.5 Functionals of the distribution functions 4.6 The surface tension from the direct correlation function 4.7 Equivalence of the two expressions for the surface tension 4.8 The spherical surface 4.9 Density fluctuations and their correlation 4.10 Local thermodynamic functions 5 MODEL FLUIDS IN THE MEAN-FIELD APPROXIMATION 5.1 Introduction: mean-field theory of a homogeneous fluid of attracting hard spheres 5.2 Liquid-gas interface in the model of attracting hard spheres 5.3 Lattice-gas model: one component 5.4 Lattice-gas model: two components 5.5 Penetrable-sphere model: theory 5.6 Penetrable-sphere model: applications 5.7 Penetrable-sphere model: spherical surfaces 6 COMPUTER SIMULATION OF THE LIQUID-GAS SURFACE 6.1 The experimental background 6.2 The methods of computer simulation 6.3 The density profile 6.4 The surface tension 6.5 Further work 7 CALCULATION OF THE DENSITY PROFILE 7.1 Introduction 7.2 Solution of the YBG equation 7.3 Approximations for the direct correlation function 7.4 Modified van der Waals theories 7.5 Perturbation theories 7.6 Surface tensions 8 THREE-PHASE EQUILIBRIUM 8.1 Introduction 8.2 Contact angles and Neumann's triangle 8.3 Spreading and Antonow's rule 8.4 The ay interface 8.5 Phase transitions in interfaces. The Cahn transition 8.6 Three-phrase line and line tension 9 INTERFACES NEAR CRITICAL POINTS 9.1 Introduction: mean-field approximation 9.2 Digression on the Ornstein-Zernike theory of the pair-correlation function 9.3 Digression on critical-point exponents 9.4 Van der Waals theory with non-classical exponents 9.5 Tricritical points 9.6 Non-critical interface near a critical endpoint 9.7 Renormalization-group theory; field-theoretical models APPENDIX 1 Thermodynamics APPENDIX 2 Dirac's delta-function NAME INDEX SUBJECT INDEX
Note de contenu : Appartient à Emmanuel Villermaux
Molecular theory of capillarity [document imprimé] / J. S. Rowlinson, Auteur ; B. Widom, Auteur . - Mineola, NY : Dover Publications, 1989 . - XI-327 p.
ISBN : 0-486-42544-4
Hardback
Langues : Français (fre)
Index. décimale : 68 Surfaces and interfaces Résumé : Tracing the history of thought on the molecular origins of surface pheomena, this volume offers a critical and detailed examination and assessment of modern theories. The opening chapters survey the earliest efforts to recapture these phenomena by using crude mechanical models of liquids as well as subsequent quasi-thermodynamic methods. A discussion of statistical mechanics leads to the application of results in mean-field approximation to some tractable but artificial model systems. More realistic models are portrayed both by computer simulation and by approximations of the precise statistical equations. Emphasis throughout the text is consistently placed on the liquid-gas surface, with a focus on liquid-liquid surfaces in the final two chapters. Unabridged republication of the edition published by Oxford University Press, Oxford, 1989. Preface. Principal symbols. Appendixes. Name Index. Subject Index. Table of Contents for Molecular Theory of Capillarity Principal symbols 1 MECHANICAL MOLECULAR MODELS 1.1 Introduction 1.2 Molecular mechanics 1.3 Capillary phenomena 1.4 The internal energy of a liquid 1.5 The continuous surface profile 1.6 The mean molecular field 2 THERMODYNAMCIS 2.1 Thermodynamics and kinetic theory 2.2 The thermodynamics of the surface 2.3 Surface functions 2.4 The spherical surface 2.5 Quasi-thermodynamics-a first look 3 THE THEORY OF VAN DER WAALS 3.1 Introduction 3.2 The surface tension 3.3 Independently variable densities 3.4 Gibbs adsorption equation in the van der Waals theory 3.5 Constraints on the range of fluctuations 4 STATISTICAL MECHANICS OF THE LIQUID-GAS SURFACE 4.1 Introduction 4.2 Distribution and correlation functions 4.3 The pressure tensor 4.4 The virial route to the surface tension 4.5 Functionals of the distribution functions 4.6 The surface tension from the direct correlation function 4.7 Equivalence of the two expressions for the surface tension 4.8 The spherical surface 4.9 Density fluctuations and their correlation 4.10 Local thermodynamic functions 5 MODEL FLUIDS IN THE MEAN-FIELD APPROXIMATION 5.1 Introduction: mean-field theory of a homogeneous fluid of attracting hard spheres 5.2 Liquid-gas interface in the model of attracting hard spheres 5.3 Lattice-gas model: one component 5.4 Lattice-gas model: two components 5.5 Penetrable-sphere model: theory 5.6 Penetrable-sphere model: applications 5.7 Penetrable-sphere model: spherical surfaces 6 COMPUTER SIMULATION OF THE LIQUID-GAS SURFACE 6.1 The experimental background 6.2 The methods of computer simulation 6.3 The density profile 6.4 The surface tension 6.5 Further work 7 CALCULATION OF THE DENSITY PROFILE 7.1 Introduction 7.2 Solution of the YBG equation 7.3 Approximations for the direct correlation function 7.4 Modified van der Waals theories 7.5 Perturbation theories 7.6 Surface tensions 8 THREE-PHASE EQUILIBRIUM 8.1 Introduction 8.2 Contact angles and Neumann's triangle 8.3 Spreading and Antonow's rule 8.4 The ay interface 8.5 Phase transitions in interfaces. The Cahn transition 8.6 Three-phrase line and line tension 9 INTERFACES NEAR CRITICAL POINTS 9.1 Introduction: mean-field approximation 9.2 Digression on the Ornstein-Zernike theory of the pair-correlation function 9.3 Digression on critical-point exponents 9.4 Van der Waals theory with non-classical exponents 9.5 Tricritical points 9.6 Non-critical interface near a critical endpoint 9.7 Renormalization-group theory; field-theoretical models APPENDIX 1 Thermodynamics APPENDIX 2 Dirac's delta-function NAME INDEX SUBJECT INDEX
Note de contenu : Appartient à Emmanuel Villermaux
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Code-barres Cote Support Localisation Section Disponibilité CG.2005.060 68 ROW Document imprimé Bureau chercheur Bureau de Emmanuel Villermaux Disponible Molecular theory of capillarity / J. S. Rowlinson
Titre : Molecular theory of capillarity Type de document : document imprimé Auteurs : J. S. Rowlinson, Auteur ; B. Widom, Auteur Editeur : Mineola, NY : Dover Publications Année de publication : 1989 Importance : XI-327 p. ISBN/ISSN/EAN : 0-486-42544-4 Note générale : Hardback
Langues : Français (fre) Index. décimale : 68 Surfaces and interfaces Résumé : Tracing the history of thought on the molecular origins of surface pheomena, this volume offers a critical and detailed examination and assessment of modern theories. The opening chapters survey the earliest efforts to recapture these phenomena by using crude mechanical models of liquids as well as subsequent quasi-thermodynamic methods. A discussion of statistical mechanics leads to the application of results in mean-field approximation to some tractable but artificial model systems. More realistic models are portrayed both by computer simulation and by approximations of the precise statistical equations. Emphasis throughout the text is consistently placed on the liquid-gas surface, with a focus on liquid-liquid surfaces in the final two chapters. Unabridged republication of the edition published by Oxford University Press, Oxford, 1989. Preface. Principal symbols. Appendixes. Name Index. Subject Index. Table of Contents for Molecular Theory of Capillarity Principal symbols 1 MECHANICAL MOLECULAR MODELS 1.1 Introduction 1.2 Molecular mechanics 1.3 Capillary phenomena 1.4 The internal energy of a liquid 1.5 The continuous surface profile 1.6 The mean molecular field 2 THERMODYNAMCIS 2.1 Thermodynamics and kinetic theory 2.2 The thermodynamics of the surface 2.3 Surface functions 2.4 The spherical surface 2.5 Quasi-thermodynamics-a first look 3 THE THEORY OF VAN DER WAALS 3.1 Introduction 3.2 The surface tension 3.3 Independently variable densities 3.4 Gibbs adsorption equation in the van der Waals theory 3.5 Constraints on the range of fluctuations 4 STATISTICAL MECHANICS OF THE LIQUID-GAS SURFACE 4.1 Introduction 4.2 Distribution and correlation functions 4.3 The pressure tensor 4.4 The virial route to the surface tension 4.5 Functionals of the distribution functions 4.6 The surface tension from the direct correlation function 4.7 Equivalence of the two expressions for the surface tension 4.8 The spherical surface 4.9 Density fluctuations and their correlation 4.10 Local thermodynamic functions 5 MODEL FLUIDS IN THE MEAN-FIELD APPROXIMATION 5.1 Introduction: mean-field theory of a homogeneous fluid of attracting hard spheres 5.2 Liquid-gas interface in the model of attracting hard spheres 5.3 Lattice-gas model: one component 5.4 Lattice-gas model: two components 5.5 Penetrable-sphere model: theory 5.6 Penetrable-sphere model: applications 5.7 Penetrable-sphere model: spherical surfaces 6 COMPUTER SIMULATION OF THE LIQUID-GAS SURFACE 6.1 The experimental background 6.2 The methods of computer simulation 6.3 The density profile 6.4 The surface tension 6.5 Further work 7 CALCULATION OF THE DENSITY PROFILE 7.1 Introduction 7.2 Solution of the YBG equation 7.3 Approximations for the direct correlation function 7.4 Modified van der Waals theories 7.5 Perturbation theories 7.6 Surface tensions 8 THREE-PHASE EQUILIBRIUM 8.1 Introduction 8.2 Contact angles and Neumann's triangle 8.3 Spreading and Antonow's rule 8.4 The ay interface 8.5 Phase transitions in interfaces. The Cahn transition 8.6 Three-phrase line and line tension 9 INTERFACES NEAR CRITICAL POINTS 9.1 Introduction: mean-field approximation 9.2 Digression on the Ornstein-Zernike theory of the pair-correlation function 9.3 Digression on critical-point exponents 9.4 Van der Waals theory with non-classical exponents 9.5 Tricritical points 9.6 Non-critical interface near a critical endpoint 9.7 Renormalization-group theory; field-theoretical models APPENDIX 1 Thermodynamics APPENDIX 2 Dirac's delta-function NAME INDEX SUBJECT INDEX
Note de contenu : Appartient à Christophe Clanet
Molecular theory of capillarity [document imprimé] / J. S. Rowlinson, Auteur ; B. Widom, Auteur . - Mineola, NY : Dover Publications, 1989 . - XI-327 p.
ISBN : 0-486-42544-4
Hardback
Langues : Français (fre)
Index. décimale : 68 Surfaces and interfaces Résumé : Tracing the history of thought on the molecular origins of surface pheomena, this volume offers a critical and detailed examination and assessment of modern theories. The opening chapters survey the earliest efforts to recapture these phenomena by using crude mechanical models of liquids as well as subsequent quasi-thermodynamic methods. A discussion of statistical mechanics leads to the application of results in mean-field approximation to some tractable but artificial model systems. More realistic models are portrayed both by computer simulation and by approximations of the precise statistical equations. Emphasis throughout the text is consistently placed on the liquid-gas surface, with a focus on liquid-liquid surfaces in the final two chapters. Unabridged republication of the edition published by Oxford University Press, Oxford, 1989. Preface. Principal symbols. Appendixes. Name Index. Subject Index. Table of Contents for Molecular Theory of Capillarity Principal symbols 1 MECHANICAL MOLECULAR MODELS 1.1 Introduction 1.2 Molecular mechanics 1.3 Capillary phenomena 1.4 The internal energy of a liquid 1.5 The continuous surface profile 1.6 The mean molecular field 2 THERMODYNAMCIS 2.1 Thermodynamics and kinetic theory 2.2 The thermodynamics of the surface 2.3 Surface functions 2.4 The spherical surface 2.5 Quasi-thermodynamics-a first look 3 THE THEORY OF VAN DER WAALS 3.1 Introduction 3.2 The surface tension 3.3 Independently variable densities 3.4 Gibbs adsorption equation in the van der Waals theory 3.5 Constraints on the range of fluctuations 4 STATISTICAL MECHANICS OF THE LIQUID-GAS SURFACE 4.1 Introduction 4.2 Distribution and correlation functions 4.3 The pressure tensor 4.4 The virial route to the surface tension 4.5 Functionals of the distribution functions 4.6 The surface tension from the direct correlation function 4.7 Equivalence of the two expressions for the surface tension 4.8 The spherical surface 4.9 Density fluctuations and their correlation 4.10 Local thermodynamic functions 5 MODEL FLUIDS IN THE MEAN-FIELD APPROXIMATION 5.1 Introduction: mean-field theory of a homogeneous fluid of attracting hard spheres 5.2 Liquid-gas interface in the model of attracting hard spheres 5.3 Lattice-gas model: one component 5.4 Lattice-gas model: two components 5.5 Penetrable-sphere model: theory 5.6 Penetrable-sphere model: applications 5.7 Penetrable-sphere model: spherical surfaces 6 COMPUTER SIMULATION OF THE LIQUID-GAS SURFACE 6.1 The experimental background 6.2 The methods of computer simulation 6.3 The density profile 6.4 The surface tension 6.5 Further work 7 CALCULATION OF THE DENSITY PROFILE 7.1 Introduction 7.2 Solution of the YBG equation 7.3 Approximations for the direct correlation function 7.4 Modified van der Waals theories 7.5 Perturbation theories 7.6 Surface tensions 8 THREE-PHASE EQUILIBRIUM 8.1 Introduction 8.2 Contact angles and Neumann's triangle 8.3 Spreading and Antonow's rule 8.4 The ay interface 8.5 Phase transitions in interfaces. The Cahn transition 8.6 Three-phrase line and line tension 9 INTERFACES NEAR CRITICAL POINTS 9.1 Introduction: mean-field approximation 9.2 Digression on the Ornstein-Zernike theory of the pair-correlation function 9.3 Digression on critical-point exponents 9.4 Van der Waals theory with non-classical exponents 9.5 Tricritical points 9.6 Non-critical interface near a critical endpoint 9.7 Renormalization-group theory; field-theoretical models APPENDIX 1 Thermodynamics APPENDIX 2 Dirac's delta-function NAME INDEX SUBJECT INDEX
Note de contenu : Appartient à Christophe Clanet
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Code-barres Cote Support Localisation Section Disponibilité CG.2006.045 68 ROW Document imprimé Bureau chercheur Bureau de Christophe Clanet Disponible